Product ID:101 3176 LIQUID DEVELOPER SYSTEM CLEANER, WORKING SOLUTION
MSDS Date:02/16/1994
FSC:6750
NIIN:01-026-9410
MSDS Number: BGFQV

EASTMAN KODAK COMPANY

343 STATE STREET
ROCHESTER, NY 14650
US

Emergency Phone: 716-722-5151

Info Phone: 800- 242-2424

Cage: 19139

EASTMAN KODAK CO US CUSTOMER SERVICE/GOVERNMENT SALES

ROCHESTER, NY 14650-3129 US

Telephone: 800-828-6203

Cage: 5K871

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: >99%

SODIUM BICHROMATE (SARA III)

CAS: 10588-01-9

RTECS: HX7700000

Fraction By Weight: <1%

OSHA PEL C 0.1 MG (CRO3)/M3

ACGIH TLV: 0.05 MG(CR)/M3; 9394

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

SULFURIC ACID (SARA III)

CAS: 7664-93-9

RTECS: WS5600000

Fraction By Weight: <1%

OSHA PEL 1 MG/M3

ACGIH TLV: 1 MG/M3; 9394

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SUSPECTED CARCINOGEN. CAUSES SEVERE
EYE BURNS. CAUSES SEVERE SKIN BURNS. HARMFUL IF ABSORBED THROUGH
THE SKIN. MAY CAUSE AN ALLERGIC SKIN REACTION. HARMFUL IF INGESTED.
MAY CAUSE IRRITATION AND BURNS OF THE DIGESTIVE TRACT AND KIDNEY
DAMAGE. INHALATION: LOW HAZARD FOR RECOMMENDED HANDLING. CHRONIC-
NONE KNOWN.
Explanation of Carcinogenicity:IARC: GROUP 1A, STRONG INORGANIC MISTS
OR VAPORS CONTAINING SULFURIC ACID, HEXAVALENT CHROMIUM COMPOUNDS.
Effects of Overexposure:EYE, SKIN & RESPIRATORY TRACT (MIST)
IRRITATION, BURNS & ALLERGIC SKIN REACTION. INGESTION CAUSES
IRRITATION AND BURNS OF THE DIGESTIVE TRACT AND KIDNEY DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION- IF SYMPTOMATIC, MOVE TO FRESH AIR. EYES-
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
SKIN- IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH
CONTAMINATED CLOTHING. INGESTION- DO NOT INDUCE VOMITING. GIVE
VICTIM A GLASS OF WATER, IF CONSCIOUS. CALL A PHYSICIAN OR POISON
CONTROL CENTER IMMEDIATELY.

Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. DRIED PRODUCT
RESIDUE CAN INCREASE THE BURNING RATE OF COMBUSTIBLE MATERIALS.

Spill Release Procedures:SOLUTION IS STRONGLY ACIDIC; AVOID CONTACT.
NEUTRALIZE WITH HYPO (SODIUM THIOSULFATE) FOLLOWED WITH SODA ASH
(SODIUM CARBONATE). PLACE SLURRY IN SUITABLE DISPOSAL CONTAINER. DO
NOT FLUSH TO SEWER, DRA IN, ETC. VENTILATE AREA (CO2 IS PRODUCED).
Neutralizing Agent:SODIUM THIOSULFATE AND SODIUM CARBONATE.

Handling and Storage Precautions:DRIED PRODUCT RESIDUE CAN ACT AS AN
OXIDIZER. KEEP FROM CONTACT WITH CLOTHING & OTHER COMBUSTIBLE
MATERIALS. REMOVE & WASH CONTAMINATED CLOTHING.
Other Precautions:KEEP CONTAINER TIGHTLY CLOSED AND AWAY FROM REDUCING
AGENTS, BASES OR COMBUSTIBLE MATERIALS. CAUTION: MIXING THIS
PRODUCT WITH THIOCYANATE PHOTOGRAPHIC SOLUTIONS MAY LIBERATE VERY
TOXIC HYDROGEN CYANI DE GAS.

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR MAY BE NEEDED IN
SPECIAL CIRCUMSTANCES.
Ventilation:GOOD MECHANICAL (GENERAL) VENTILATION SHOULD BE SUFFICIENT.
LOCAL MAY BE REQUIRED IN SPECIAL CIRCUMSTANCES.
Protective Gloves:IMPERVIOUS
Eye Protection:GOGGLES/FACE SHIELD
Other Protective Equipment:RUBBER APRON.
Work Hygienic Practices:AVOID CONTACT WITH SOLUTION. WASH THOROUGHLY
AFTER USE & BEFORE EATING.LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health

HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:24
Vapor Density:0.6
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, ODORLESS.
Percent Volatiles by Volume:99

Stability Indicator/Materials to Avoid:YES
REDUCING AGENTS, BASES, COMBUSTIBLE MATERIALS.
Stability Condition to Avoid:FLAME AND WATER
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
OXIDES OF SULFUR.

Waste Disposal Methods:MANY MUNICIPAL SEWER CODES REGULATE THE
DISCHARGE OF CHROMIUM. EXHAUSTED SYSTEMS CLEANER SHOULD BE
COLLECTED & DISPOSED BY A LICENSED CHEMICAL WASTE DISPOSAL AGENCY.
THE CHROMIUM CAN BE REDUCED & COLL ECTED FOR DISPOSAL.DISPOSE IAW
FED & STATE LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.